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Tuesday, 14 June 2016
Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES
Published Date 15 November 2016, Vol.386:115–124,doi:10.1016/j.apsusc.2016.06.004 Title Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES
Author
Shanshan Jia a
Ming Liu a
Yiqiang Wu a,b,,
Sha Luo a
Yan Qing a,b,,
Haibo Chen a
aCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
bHunan Provincial Collaborative Innovation Center for High-efficiency Utilization of Wood and Bamboo Resources, Central South University of Forestry and Technology, Changsha 410004, China
Received 27 March 2016. Revised 31 May 2016. Accepted 2 June 2016. Available online 3 June 2016.
Highlights
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Superhydrophobic surface on wood substrates was efficiently fabricated using nanoparticles modified by VTES.
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The superhydrophobic surface exhibited a CA of 154° and a SAclose to 0°.
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The superhydrophobic surface showed a durable and robust wear-resistance performance.
Abstract
In this study, an efficient, facile method has been developed for fabricating superhydrophobic surfaces on wood substrates using silica nanoparticles modified by VTES. The as-prepared superhydrophobic wood surface had a water contact angle of 154° and water slide angle close to 0°. Simultaneously, this superhydrophobic wood showed highly durable and robust wear resistance when having undergone a long period of sandpaper abrasion or being scratched by a knife. Even under extreme conditions of boiling water, the superhydrophobicity of the as-prepared wood composite was preserved. Characterizations by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Fourier transform infrared spectroscopy showed that a typical and tough hierarchical micro/nanostructure was created on the wood substrate and vinyltriethoxysilane contributed to preventing the agglomeration of silica nanoparticles and serving as low-surface-free-energy substances. This superhydrophobic wood was easy to fabricate, mechanically resistant and exhibited long-term stability. Therefore, it is considered to be of significant importance in the industrial production of functional wood, especially for outdoor applications.
Graphical abstract
Highly wear-resistance superhydrophobic surface on wood substrates was fabricated using silica nanoparticles modified by VTES.
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