Published Date
References
For further details log on website :
http://link.springer.com/article/10.1007%2Fs12588-014-9069-9
, Volume 18, Issue 1, pp 125-134
First online:
Title
Morphology and thermo mechanical properties of pp/ps nanocomposites
Author
Abstract
The immiscible polypropylene (PP)/polystyrene (PS) blends and theirs organoclay 10A (Cloisite10A) nanocomposites with different contents were prepared via melt blending into a co-rotating twin screw extruder and the test samples were molded by injection molding. The 10A is an anisotropic layered silicate and the effect PP/PS ratio, 10A different content on melt and crystallization enthalpy were determined by DSC. The T g , storage modulus (E’), and tanδ measurements were obtained by DMA. The domains reduction of PS in the PP with addition 10A was investigated by Scanning Electronic Microscope (SEM). There is a decrease in PS particles size in PP/PS blends containing 10A. The crystallinity degree of PP seems to reduction with the addition of PS phase and 10A. The E’ of the PP/PS 90/10/0 blends showed slightly changes between Neat PP and PP/PS/10A nonetheless the nanocomposites 3 and 5 %wt had a small rise in the storage modulus between −50 and 0 °C.
Keywords
Polypropylene Polystyrene Organoclay BlendsReferences
- 1.Asha KK, Tresa SG, Anjana R, Newly J, Georg KE (2013) Effect of modified kaolin clays on the mechanical properties of polypropylene/polystyrene blends. J Appl Polym Sci. doi:10.1002/APP.38043
- 2.Utracki LA (1989) Poymer Alloys and Blends. Thermodynamics and Rheology, New York
- 3.Yoshida K, Kawamura T, Terano M, Nitta K (2008) Effects of bulk morphology on the mechanical properties of melt-blended PP/PS blends. J A Pol Sci. doi:10.1002/app.28014
- 4.Yuan HY, Ching YL, Jui MY, Wei HL (2003) Preparation and properties of poly(vinyl alcohol)–clay nanocomposite materials. Polymer. doi:10.1016/S0032–3861(03)00062–4
- 5.Silva RP, Salles CA, Mauler RS, Oliveira RVB (2010) Avaliação da morfologia e propriedades termo-mecânicas em nanocompósitos de PVC. Pol Cien Tecn. doi:10.1590/S0104–14282010005000012
- 6.Silva RP, Salles CA, Mauler RS, Oliveira RVB (2010) Investigation of the thermal, mechanical and morphological properties of poly(vinyl chloride)/polyhedral oligomeric silsesquioxane nanocomposites. Pol Int. doi:10.1002/pi.2851
- 7.Zhu Y, Xu Y, Tong L, Xu Z, Fang Z (2008) Influence of polarity on the preferential intercalation behavior of clay in immiscible polypropylene/polystyrene blend. J A Pol Sci. doi:10.1002/app.28927
- 8.Suprakas SR, Steve P, Mosto B, Leszek U (2004) Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends. Polymer. doi:10.1016/j.polymer.2004.10.009
- 9.Yurekli K, Karim A, Amis EJ, Krishnamoorti R (2003) Influence of layered silicates on the phase-separated morphology of PS − PVME blends. Macromol. doi:10.1021/ma020755l
- 10.Zhu Y, Ma H, Tong L, Fang Z (2008) Preferential intercalation behavior of clay and its effect on the thermal degradation in immiscible PP/PS blends. C J Pol Sci. doi:10.1142/S0256767908003540
- 11.Yong W, Yan X, Qin Z, Xiao LG, Qiang F (2003) The morphology and mechanical properties of dynamic packing injection molded PP/PS blends. Polymer. doi:10.1016/S0032–3861(03)00011–9
- 12.Wang Y, Zhang Q, Fu Q (2003) Compatibilization of immiscible poly(propylene)/polystyrene blends using clay. Macromol Rap Com. doi:10.1002/marc.200390026
- 13.Yan Z, Yuzhen X, Lifang T, Zhongbin X, Zhengping F (2008) Influence of polarity on the preferential intercalation behavior of clay in immiscible polypropylene/polystyrene blend. J Appl Polym Sci. doi:10.1002/app.28927
- 14.Ray S, Suprakas P, Steve BM (2004) Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends. Polymer. doi:10.1016/j.polymer.2004.10.009
- 15.Rajkiran RT, Paul DR (2011) Effect of organoclay on the morphology, phase stability and mechanical properties of polypropylene/polystyrene blends. Polymer. doi:10.1016/j.polymer.2011.01.019
- 16.Huang H, Han B, Wang L, Miao N, Mo H, Zhou NL, Ma ZM, Zhang J, Shen J (2011) Crystallization kinetics of polypropylene composites filled with nano calcium carbonate modified with maleic anhydride. J Appl Polym Sci. doi:10.1002/app.32842
- 17.Gao J, Fu X, Ding M, Fu Q (2010) Studies on partial compatibility of PP and PS. C J Pol Sci. doi:10.1007/s10118–010–9150–6
- 18.Zhang YQ, Lee JH, Rhee JM, Rhee KY (2004) Polypropylene–clay nanocomposites prepared by in situ grafting-intercalating in melt. Comp Sci Tech. doi:10.1016/j.compscitech.2003.10.014
- 19.Amash A, Zugenmaier P (1997) Thermal and dynamic mechanical investigations on fiber-reinforced polypropylene composites. J Appl Polym Sci. doi:10.1002/(SICI)1097–4628
- 20.Prasanna KS, Mural SM, Sanjay KNSA (2011) Polypropylene/high impact polystyrene blend nanocomposites obtained from E-waste: evaluation of mechanical, thermal and morphological properties. Int J Plast Technol. doi:10.1007/s12588–011–9005–1
- 21.Halimatudahliana A, Ismail H, Nasir A (2002) Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend. Pol Test. doi:10.1016/S0142–9418(01)00079–4
- 22.Santos KS (2011) Efeito das Condições de Processo sobre morfologia de Nanocompositos de Polipropileno com argila organofílica. UFRGS, Tese de Doutorado
- 23.Jia QM, Zheng M, Zhu YC, Li JB, Xu CZ (2007) Effects of organophilic montmorillonite on hydrogen bonding, free volume and glass transition temperature of epoxy resin/polyurethane interpenetrating polymer networks. Europ Pol J. doi:10.1016/j.eurpolymj.2006.10.016
- 24.Liv Y, Huang Y, Kong M, Li G (2013) Improved thermal oxidation stability of polypropylene films in the presence of β-nucleating agent. Pol Test. doi:10.1016/j.polymertesting.2012.10.008
- 25.Santos K, Demori R, Mauler RS, Liberman SA, Oviedo MAS (2009) The influence of screw configurations and feed mode on the dispersion of organoclay on PP. Comp Part A: App Sci Man. doi:10.1016/j.compositesa.2009.05.009
- 26.Thirtha V, Lehman R, Nosker T (2006) Morphological effects on glass transition behavior in selected immiscible blends of amorphous and semicrystalline polymers. Polymer. doi:10.1016/j.polymer. 2006.05.014
- 27.Macaúbas PHP, Demarquette N (2001) Morphology development and melt linear viscoelastic properties of (PA6/PP/PS) ternary blend systems. Polymer. doi:10.1177/0095244309104461
- 28.Asha KK, Tresa SG, Anjana R, Newly J, George KE (2013) Effect of modified kaolin clays on the mechanical properties of polypropylene/polystyrene blends. J Appl Polym Sci. doi:10.1002/app.38043
- 29.Aklonis JJ, Macknight WJ (1983) Introduction to Polymer Viscoelasticity, 2nd edn. Wiley, New York, pp 295–320
- 30.Menard KP (1999) Dynamic Mechanical Analysis. A practical Introduction CRC Press, New YorkCrossRef
- 31.Sperling LH (2006) Introduction to Physical Polymer Science. Bethlehem, Pennsylvania
For further details log on website :
http://link.springer.com/article/10.1007%2Fs12588-014-9069-9
No comments:
Post a Comment