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For further details log on website :
http://link.springer.com/article/10.1007/s13595-015-0531-4
, Volume 73, Issue 3, pp 559-570
First online:
Title
New alternatives for wood preservation based on thermal and chemical modification of wood— a review
- Author
- Philippe Gérardin
Abstract
Key message
Increasing environmental pressures appearing over the last few years have led to important changes in the field of wood protection. In this context, new technologies, based either on thermal or chemical modifications, suggest increasing interest in prospect of programmed ban of biocide products.
• Context
The evolution of the regulations on the use of biocide products has led to important changes in the field of wood preservation, leading to an increasing interest for non-biocide treatments like thermal or chemical modifications to face to the programmed ban of biocide products.
• Aims
The paper reviews the different non-biocide alternatives developed currently on an industrial scale, highlighting their main characteristics and applications.
• Results
Different treatments have been developed on an industrial scale involving mainly thermal modifications and acetylation, furfurylation and DMDHEU constituting already available solutions.
• Conclusion
Different non-biocide alternatives already exist and will become more important in the next decades due to the increasing legislative pressure driven by environmental considerations.
Keywords
Acetylation Chemical modification DMDHEU Furfurylation Thermo-modified wood Heat treatment Non-biocide treatmentReferences
- Abibois (2012) Traitement haute température des bois, available at http://abibois.com/category/4-preservation-et-entretien?download=14
- Ajji Z (2006) Preparation of pinewood/polymer/composites using gamma irradiation. Radiat Phys Chem 75:1075–1079CrossRef
- Alén R, Kotilainen R, Zaman A (2002) Thermochemical behaviour of Norway spruce (Picea abies) at 180-225 °C. Wood Sci Technol 36:163–171CrossRef
- Beckers EPJ, De Meijer M, Mititz H, Stevens M (1998) Performance of finishes on wood that is chemically modified by acetylation. J Coatings Technol 70:59–67CrossRef
- Boonstra MG, Pizzi A, Tekely P, Pendlebury J (1996) Chemical modification of Norway spruce and scots pine: A 13C NMR CP-MAS study of the reactivity and reactions of polymeric wood components with acetic anhydride. Holzforschung 50:215–220CrossRef
- Boonstra MJ, Van Acker J, Kegel EV, Tjeerdsma BF (2007) Strength properties of thermally modified sofwoods and its relation to polymeric structural wood constituents. Ann For Sci 64:679–690CrossRef
- Borrega M, Kärenlampi P (2008) Effect of relative humidity on thermal degradation of Norway spruce (Picea abies) wood. J Wood Sci 54:323–328CrossRef
- Brelid PL, Simonson R (1999) Acetylation of solid wood using microwave heating: Part 2. Experiments in laboratory scale. Holz Roh Werkst 57:383–389CrossRef
- Brelid PL, Simonson R, Risman PO (1999) Acetylation of solid wood using microwave heating: Part 1. Studies of dielectric properties. Holz Roh Werkst 57:259–2639CrossRef
- Candelier K, Dumarçay S, Pétrissans A, Desharnais L, Gérardin P, Pétrissans M (2013a) Comparison of chemical composition and decay durability of heat treated wood cured at a same temperature under different inert atmospheres: nitrogen or vacuum. Polym Degrad Stab 98:677–681CrossRef
- Candelier K, Dumarçay S, Pétrissans A, Desharnais L, Gérardin P, Pétrissans M (2013b) Comparison of mechanical properties of heat treated beech wood cured under nitrogen or vacuum. Polym Degrad Stab 98:1762–1765CrossRef
- Chang ST, Chang HT (2001) Comparisons of the photostability of esterified wood. Polym Degrad Stab 71:261–266CrossRef
- Cleland MR, Galloway RA, Berejka AJ, Montoney D, Driscoll M, Smith L, Scott Larsen L (2009) X-ray initiated polymerization of wood impregnants. Radiat Phys Chem 78:535–538CrossRef
- Devi RR, Maji TK (2007) Effect of glycidyl methacrylate on the physical properties of wood-polymer composites. Polym Compos 28:1–5CrossRef
- Devi RR, Maji TK, Banerjee AN (2004) Studies on dimensional stability and thermal properties of rubber wood chemically modified with styrene and glycidyl methacrylate. J Appl Polym Sci 93:1938–1945CrossRef
- Dieste A, Krause A, Militz H (2008a) Modification of Fagus sylvatica (L.) with 1,3-dimethylol-4,5- dihydroxyethylene urea (DMDHEU): Part 1. Estimation of heat adsorption by the isosteric method (Hailwood-Horrobin model) and by solution calorimetry. Holzforschung 62:577–583CrossRef
- Dieste A, Krause A, Bollmus S, Militz H (2008b) Physical and mechanical properties of plywood produced with 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU)-modified veneers of Betula sp. and Fagus sylvatica. Holz Roh Werkst 66:281–287CrossRef
- Dieste A, Krause A, Mai C, Sèbe G, Grelier S, Militz H (2009a) Modification of Fagus sylvatica L. with 1,3-dimethylol-4,5-dihydroxy ethylene urea (DMDHEU). Part 2: pore size distribution determined by differential scanning calorimetry. Holzforschung 63:89–93CrossRef
- Dieste A, Krause A, Bollmus S, Militz H (2009b) Gluing ability of plywood produced with DMDHEU-modified veneers of Fagus sp., Betula sp., and Picea sp. Int J Adhes Adhes 29:206–209CrossRef
- El-Awady NI (1999) Wood polymer composites using thermal and radiation techniques. J Reinf Plast Compos 18:1367–1374
- Epmeier H, Westin M, Rapp A (2004) Differently modified wood: comparison of some selected properties. Scand J For Res Suppl 19:31–37CrossRef
- Epmeier H, Johansson M, Kliger R, Westin M (2007) Material properties and their interrelation in chemically modified clear wood of Scots pine. Holzforschung 61:34–42CrossRef
- Gago J, López A, Santiago J, Acevedo M, Rodríguez J (2007) Wood-polymer composites obtained by gamma irradiation. AIP Conf Proc 947:481–482CrossRef
- Gascón-Garrido P, Oliver-Villanueva JV, Ibiza-Palacios MS, Militz H, Mai C, Adamopoulos S (2013) Resistance of wood modified with different technologies against Mediterranean termites (Reticulitermes spp.). Int Biodeterior Biodegrad 82:13–16CrossRef
- Gobakken LR, Westin M (2008) Surface mould growth on five modified wood substrates coated with three different coating systems when exposed outdoors. Int Biodeterior Biodegrad 62:397–402CrossRef
- Gosselink RJA, Krosse AMA, Van der Putten JC, Van der Kolk JC, De Klerk-Engels B, Van Dan JEG (2004) Wood preservation by low-temperature carbonisation. Ind Crop Prod 19:3–12CrossRef
- Hakkou M, Pétrissans M, Gérardin P, Zoulalian A (2005a) Investigation of wood wettability changes during heat treatment on the basis of chemical analysis. Polym Degrad Stab 89:1–5CrossRef
- Hakkou M, Pétrissans M, Gérardin P, Zoulalian A (2005b) Wettability changes and mass loss during heat treatment of wood. Holzforschung 59:35–37CrossRef
- Hakkou M, Pétrissans M, Zoulalian A, Gérardin P (2005c) Investigation of wood wettability changes during Heat treatment on the basis of chemical analysis. Polym Degrad Stab 89:165CrossRef
- Hakkou M, Pétrissans M, Gérardin P, Zoulalian A (2006) Investigation of the reasons for fungal durability of heat-treated beech wood. Polym Degrad Stab 91:393–397CrossRef
- Hill C (2005) Chemical modification of wood (II): reaction with other chemicals in wood modification – chemical, thermal and other processes. John Wiley & Sons 77-97
- Hill CAS, Hale MD, Ormondroyd GA, Kwon JH, Forster SC (2006) Decay resistance of anhydride-modified Corsican pine sapwood exposed to the brown rot fungus Coniophora puteana. Holzforschung 60:625–629CrossRef
- Hill CAS, Curling SF, Kwon JH, Marty V (2009) Decay resistance of acetylated and hexanoylated hardwood and softwood species exposed to Coniophora puteana. Holzforschung 63:619–625CrossRef
- Jebrane M, Harper D, Labbé N, Sèbe G (2011) Comparative determination of the grafting distribution and viscoelastic properties of wood blocks acetylated by vinyl acetate or acetic anhydride. Carbohydr Polym 84:1314–1320CrossRef
- Jiang T, Gao H, Sun JP, Xie YJ, Li XR (2014) Impact of DMDHEU resin treatment on the mechanical properties of poplar. Polym Polym Compos 22:669–674
- Kamdem P, Pizzi A, Guyonnet R, Jermannaud A (1999) Durability of heat-treated wood. International Research Group on Wood Preservation. Document no. IRG/WP 99-40145
- Kamdem DP, Pizzi A, Jermannaud A (2002) Durability of heat-treated wood. Holz Roh Werkst 60:1–6CrossRef
- Kim DY, Yochiharu N, Masahisa W, Shigenori K, Takeshi O (2001) Thermal decomposition of cellulose crystallites in wood. Holzforschung 55:521–524CrossRef
- Kumar M, Srivastav A, Sah PL, Jaidi MGH (2008) Recent trends in low grade wood polymer composites modification techniques and their mechanical and thermal characteriztion. Advances in Heterogeneous Material Mechanics 2008: proceedings of the 2nd international conference on heterogeneous material mechanics, ICHMM 2008 p. 998
- Lande S, Westin M, Schneider M (2004a) Properties of furfurylated wood. Scand J For Res Suppl 19:22–30CrossRef
- Lande S, Eikenes M, Westin M (2004b) Chemistry and ecotoxicology of furfurylated wood. Scand J For Res Suppl 19:14–21CrossRef
- Lande S, Westin M, Schneider MH (2004c) Eco-efficient wood protection: furfurylated wood as alternative to traditional wood preservation. Manag Environ Qual 15:529–540CrossRef
- Lande S, Westin M, Schneider M (2008) Development of modified wood products based on furan chemistry. Mol Cryst Liq Cryst 484:1/[367]–12/[378]CrossRef
- Lekounougou S, Pétrissans M, Jacquot JP, Gelhaye E, Gérardin P (2009) Effect of heat treatment on extracellular enzymatic activities involved in beech wood degradation by Trametes versicolor. Wood Sci Technol 43:331–341CrossRef
- Li Y, Liu Y, Shi J, Li G (2010) Structure and property of PGMA/wood composite. Adv Mater Res 87–88:456–461CrossRef
- Lopes DB, Mai C, Militz H (2014) Marine borers resistance of chemically modified Portuguese wood. Maderas-Ciencia Y Tecnologia 16:109–124
- Mathias LJ, Wright JR (1989) New wood-polymer composites: impregnation and in situ polymerization of hydroxymethylacrylates. Am Chem Soc Polym Prepr Div Polym Chem 30:233–234
- Militz H (2002) Thermal treatment of wood European process and their background. International Research Group on Wood Preservation. Document no. IRG/WP 02-40241.
- Minato K, Ito Y (2004) Analysis of the factors influencing the acetylation rate of wood. J Wood Sci 50:519–523CrossRef
- Mohareb A, Sirmah P, Desharnays L, Dumarçay S, Pétrissans M, Gérardin P (2010) Effect of extractives on conferred and natural durability of Cupressus lusitanica heartwood. Ann For Sci 67:504CrossRef
- Mohebby B, Militz H (2010) Microbial attack of acetylated wood in field soil trials. Int Biodeterior Biodegrad 64:41–50CrossRef
- Mohebby B, Gorbani-Kokandeh M, Soltani M (2009) Springback in acetylated wood based composites. Constr Build Mater 23:3103–3106CrossRef
- Nguila Inari G, Mounguengui S, Dumarçay S, Pétrissans M, Gérardin P (2007) Evidence of char formation during heat treatment by pyrolysis. Polym Degrad Stab 92:997–1002CrossRef
- Nguila Inari G, Pétrissans M, Pétrissans A, Gérardin P (2009) Elemental composition of wood as a potential marker to evaluate heat treatment intensity. Polym Degrad Stab 94:365–368CrossRef
- Nguila Inari IG, Pétrissans M, Dumarcay S, Lambert J, Ehrhardt JJ, Šernek M, Gérardin P (2011) Limitation of XPS for analysis of wood species containing high amounts of lipophilic extractives. Wood Sci Technol 45:369–382
- Nordstierna L, Lande S, Westin M, Karlsson O, Furó I (2008) Towards novel wood-based materials: chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR. Holzforschung 62:709–713CrossRef
- Nuopponen M, Vuorinen T, Jamsa S, Viitaniemi P (2003) The effects of a heat treatment on the behaviour of extractives in softwood by FTIR spectroscopic methods. Wood Sci Technol 37:109–115CrossRef
- Obataya E, Minato K (2009) Potassium acetate-catalyzed acetylation of wood at low temperatures II: vapor phase acetylation at room temperature. J Wood Sci 55:23–26CrossRef
- Özmen N (2007) Dimensional stabilisation of fast growing forest species by acetylation. J Appl Sci 7:710–714CrossRef
- Papadopoulos AN (2008) The effect of acetylation on bending strength of finger jointed beech wood (Fagus sylvatica L.). Holz Roh Werkst 66:309–310CrossRef
- Petrič M, Knehtl B, Krause A, Militz H, Pavlič M, Pétrissans M, Rapp A, Tomažič M, Welzbacher C, Gérardin P (2007) Wettability of waterborne coatings on chemically and thermally modified pine wood. J Coat Technol Res 4:203–206CrossRef
- Pétrissans M, Gérardin P, Elbakali D, Serraj M (2003) Wettability of heat-treated wood. Holzforschung 57:301–307CrossRef
- Peydecastaing J, Vaca-Garcia C, Borredon1 E, El Kasmi S (2009) Hydrophobicity of mixed acetic-fatty wood esters, European conference on wood modification
- Pilgard A, Andreas T, Albert NT, Zeeland V, Gosselink JA, Westin M (2010a) Toxic hazard and chemical analysis of leacheates from furfurylated wood. Environ Toxicol Chem 29:1918–1924PubMed
- Pilgard A, De Vetter L, Van Acker J, Westin M (2010b) Toxic hazard of leachates from furfurylated wood: comparisons between two different aquatic organisms. Environ Toxicol Chem 29:1067–1071PubMed
- Pu Y, Ragauskas AJ (2005) Structural analysis of acetylated hardwood lignins and their photoyellowing properties. Can J Chem 83:2132–2139CrossRef
- Rafidah KS, Hill CAS, Ormondroyd GA (2006) Dimensional stabilization of rubberwood (Hevea brasiliensis) with acetic or hexanoic anhydride. J Trop For Sci 18:261–268
- Ramsden MJ, Blake FSR, Fey NJ (1997) The effect of acetylation on the mechanical properties, hydrophobitity and dimensional stability of Pinus sylvestris. Wood Sci Technol 31:97–104
- Rowell RM (2005) Chemical modification of wood in handbook of wood chemistry and wood composites, Taylor and Francis 381-420
- Rowell RM (2006) Acetylation of wood. For Prod J 56:4–12
- Rowell RM, Banks WB (1987) Tensile strength and toughness of acetylated pine and lime flakes. Brit Polym J 19:479–482CrossRef
- Rowell RM, Wang RHS, Hyatt JA (1985) Reaction of aspen and southern pine wood flakes with gaseous ketene. p. 221. Conference paper
- Rowell RM, Tillman AM, Simonson R (1986) Vapor phase acetylation of southern pine, Douglas-fir, and aspen wood flakes. J Wood Chem Technol 6:293–309CrossRef
- Rowell RM, Youngquist JA, Sachs IB (1987) Adhesive bonding of acetylated aspen flakes, Part 1. Surface changes, hydrophobicity, adhesive penetration and strength. Int J Adhes Adhes 7:183–188CrossRef
- Santos JA (2000) Mechanical behaviour of eucalyptus wood modified by heat. Wood Sci Technol 34:39–43CrossRef
- Schneider MH (1995) New cell wall and cell lumen wood polymer composites. Wood Sci Technol 29:121–127CrossRef
- Sheikh N, Taromi FA (1993) Radiation induced polymerization of vinyl monomers and their application for preparation of wood-polymer composites. Radiat Phys Chem 42:179–182CrossRef
- Sivonen H, Maunu SL, Sundholm F, Jamsa S, Viitaniemi P (2002) Magnetic resonance studies of thermally modified wood. Holzforschung 56:648–654CrossRef
- Şolpan D, Güven O (1998) Comparison of the dimensional stabilities of oak and cedar wood preserved by in situ copolymerization of allyl glycidyl ether with acrylonitrile and methyl methacrylate. Angew Makromol Chem 259:35–37
- Şolpan D, Güven O (1999a) Preparation and properties of some wood/(co)polymer composites. Angew Makromol Chem 269:30–35CrossRef
- Şolpan D, Güven O (1999b) Preservation of beech and spruce wood by allyl alcohol-based copolymers. Radiat Phys Chem 54:583–591CrossRef
- Şolpan D, Güven O (1999c) Modification of some mechanical properties of cedar wood by radiation induced in-situ copolymerization of allyl glycidyl ether with acrylonitrile and methyl methacrylate. Iran Polym J 8:73–81
- Şolpan D, Güven O (1999d) Improvement of mechanical stability of Beechwood by radiation-induced in situ copolymerization of allyl glycidyl ether with acrylonitrile and methyl methacrylate. J Appl Polym Sci 71:1515–1523CrossRef
- Soulounganga P, Loubinoux B, Wozniak E, Lemor A, Gérardin P (2004) Improvement of wood properties by impregnation with polyglycerol methacrylate. Holz Roh Werkst 62:281–285CrossRef
- Stamm AJ, Seborg RM (1951) Resin-treated laminated, compressed wood – compreg. USDA Forest Service, Forest Product Laboratory, report no. 1381
- Stamm AJ, Seborg RM (1962) Resin-treated laminated, compressed wood – impreg. USDA Forest Service, Forest Product Laboratory, report no. 1380
- Stingl R, Patzelt M, Teischinger A (2002) Ein-und Rücklick. in ausgewählte Verfahren der thermischen Modifikation. In: Lignovisionen, Modifiziertes Holz Eigenschaften und Märkte. 7-99
- Šušteršic Ž, Mohareb A, Chaouch M, Pétrissans M, Petrič M, Gérardin P (2010) Prediction of decay resistance of heat treated wood on the basis of its elemental composition. Polym Degrad Stab 95:94–97CrossRef
- Temiz A, Terziev N, Eikenes M, Hafren J (2007) Effect of accelerated weathering on surface chemistry of modified wood. Appl Surf Sci 253:5355–5362CrossRef
- Thomas PT, Babu BRS, Neelakandan K (1993) Studies on certain wood-plastic-composites prepared by gamma irradiation. B Mater Sci 16:73–83CrossRef
- Tillman AM (1987) Chemical modification of lignocellulosic materials: a comparison of processes. Chalmers Teckniska Hogskola, Doktorsavhandlingar 643:52
- Tjeerdsma BF, Boonstra M, Pizzi A, Tekely P, Militz H (1998) Characterisation of the thermally modified wood: molecular reasons for wood performance improvement. Holz Roh Werkst 56:149–153CrossRef
- Verma P, Dyckmans J, Militz H, Mai C (2008) Determination of fungal activity in modified wood by means of micro-calorimetry and determination of total esterase activity. Appl Microbiol Biotechnol 80:125–133CrossRefPubMedPubMedCentral
- Verma P, Junga U, Militz H, Mai C (2009) Protection mechanisms of DMDHEU treated wood against white and brown rot fungi. Holzforschung 63:371–378CrossRef
- Vetter LD, Depraetere G, Janssen C, Stevens M, Acker JV (2008) Methodology to assess both the efficacy and ecotoxicology of preservative-treated and modified wood. Ann For Sci 65:504p1–504p10CrossRef
- Wang CL, Lin TS, Li MH (2002) Decay and termites resistance of planted tree sapwood modified by acetylation. Taiwan J For Sci 17:483–490
- Weiland JJ, Guyonnet R (2001) Physicochemical study of thermal treatment of wood. Récents Progrès en Génies des Procédés 15:195–202
- Weiland JJ, Guyonnet R (2003) Study of chemical modifications and fungi degradations of thermally modified wood using DRIFT spectroscopy. Holz Roh Werkst 61:216–220
- Welzbacher CR, Brischke C, Rapp AO (2007) Influence of treatment temperature and duration on selected biological, mechanical, physical and optical properties of thermally modified timber. Wood Mater Sci Eng 2007:66–76CrossRef
- Wikberg H, Maunu SL (2004) Characterization of thermally modified hard and softwoods by CP/MAS 13NMR. Carbohydr Polym 58:461–6CrossRef
- Xie Y, Krause A, Mai C, Militz H, Richter K, Urban K, Evans PD (2005) Weathering of wood modified with the N-methylol compound 1,3-dimethylol-4,5-dihydroxyethyleneurea. Polym Degrad Stab 89:189–199CrossRef
- Xie Y, Krause A, Militz H, Mai C (2006) Coating performance of finishes on wood modified with an N-methylol compound. Prog Org Coat 57:291–300CrossRef
- Xie Y, Krause A, Militz H, Turkulin H, Richter K, Mai C (2007) Effect of treatments with 1,3-dimethylol-4,5-dihydroxy-ethyleneurea (DMDHEU) on the tensile properties of wood. Holzforschung 61:43–50CrossRef
- Yalinkilic MK, Gezer ED, Takahashi M, Demirci Z, Ilhan R, Imamura Y (1999) Boron addition to non- or low-formaldehyde cross-linking reagents to enhance biological resistance and dimensional stability of wood. Holz Roh Werkst 57:351–357CrossRef
- Yildiz S, Gümüskaya E (2005) The effects of thermal modification on crystalline structure of cellulose in soft and hardwood. Build Environ 42:62–67CrossRef
- Yildiz UC, Yildiz S, Gezer ED (2005) Mechanical and chemical behavior of beech wood modified by heat. Wood Fiber Sci 37:456–461
- Yildiz S, Gezer ED, Yildiz U (2006) Mechanical and chemical behavior of spruce wood modified by heat. Build Environ 41:1762–1766CrossRef
- Yuan J, Hu YC, Li LF, Cheng FC (2013) The mechanical strength change of wood modified with DMDHEU. Bioresources 8:1076–1088
- Zhang Y, Zhang SY, Yang DQ, Wan H (2006) Dimensional stability of wood-polymer composites. J Appl Polym Sci 102:5085–5094CrossRef
For further details log on website :
http://link.springer.com/article/10.1007/s13595-015-0531-4
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