Blog List

Monday 15 August 2016

Molecular and Cell Wall Structure of Wood

Published Date
Volume 3 of the series NATO Conference Series pp 7-51

Title 

Molecular and Cell Wall Structure of Wood

  • Author 
  • Richard E. Mark

Abstract

To the materials scientist, the word “fiber” connotes a slender, thread-like structure with substantial mechanical properties. The term includes a vast array of natural and synthetic materials — derived from metals, polymers, ceramic and vitreous materials, and from diverse animal and plant origins. Wood is a fibrous material in the main. In the woods produced by conifers, some 90 per cent of the volumetric composition and approximately 95 per cent of the dry mass can be attributed to cellulosic fibers known as tracheids. Lignified cellulosic fibers of various kinds form the bulk of virtually all woods. Accordingly, our attention focuses on the constituent fibers when we consider the material wood from a materials science standpoint. In wood as well as in other plant-derived materials, the fibers are in reality the exoskeletons of once-living, elongate cells that originated from a meristem. The cells each have a lumen, or hollow center.

References

  1. 1.
    Adler, E. 1977. Lignin chemistry — past, present and future. Wood SciTechnol11:169–218.CrossRef
  2. 2.
    Barber, N. F. 1969. The shrinkage of wood, theoretical models. I.P.P.S. Conference on Science of Materials, Auckland, N. Z. InfSer71, NZDSIR 184.
  3. 3.
    Barber, N. F. and Meylan, B. A. 1964. The anisotropic shrink age of wood, a theoretical model. Holzforsch18; 146–156.CrossRef
  4. 4.
    Barrett, J. D., and Schniewind, A. P. 1973. Three-dimensional finite-element models of cylindrical wood fibers. Wood and Fiber 5(3);215–225.
  5. 5.
    Blackwell, J., and Kolpak, F. J. 1975. The cellulose micro fibril as an imperfect array of elementary fibrils. Macro-molecules 8:322–326.ADSCrossRef
  6. 6.
    Bowden, P. B. 1968. The elastic modulus of an amorphous glassy polymer. Polymer 9(9):449–454.CrossRef
  7. 7.
    Browning, B. L. 1963. The composition and chemical reactions of wood. in “The Chemistry of Wood,” B. L. Browning, Ed., Interscience, New York 57–101.
  8. 8.
    Bucher, H. 1958. Discontinuities in the microscopic structure of wood fibres, in “Fundamentals of Papermaking Fibers,” F. Bolam, Ed., Brit. Pap. Bd. Assoc., Surrey 7–26.
  9. 9.
    Caulfield, D. F. 1971. sizes in wet and dry Valonia ventricosaTextile ResJ41;267.
  10. 10.
    Fergus, B. J. and Goring, D. A. I. 1970. The distribution of lignin in birch wood as determined by ultraviolet microscopy. Holzforsch24(4);118–124.CrossRef
  11. 11.
    Frey-Wyssling, A. and Mühlethaler, K. 1965. “Ultrastructural Plant Cytology,” Elsevier Pub. Co., New York.
  12. 12.
    Frey-Wyssling, A., Mühlethaler, K. and Muggli, R. 1966. Elementarfibrillen als Grundbausteine der nativen Cellulose. Holz Roh-Werkstoff 24:443–444.CrossRef
  13. 13.
    Gardner, K. H., and Blackwell, J. 1974. The structure of native cellulose. Biopolymers 13:1975–2001.CrossRef
  14. 14.
    Gillis, P. P. 1969. Effect of hydrogen bonds on the axial stiffness of crystalline native cellulose. J. Polymer Sci7:783–794.
  15. 15.
    Gillis, P. P. and Mark, R. E. 1973. Analysis of shrinkage, swelling and twisting of pulp fibers. Cellulose Chem. Tech2(2):209–234.
  16. 16.
    Goring, D. A. I. 1971. Polymer properties of lignin and lignin derivatives, “Lignins, Occurrence, Formation, Structure and Reactions,” K. V. Sarkanen and C. H. Ludwig, eds, Wiley-Interscience, New York 695–768.
  17. 17.
    Hill, R. 1963. Elastic properties of reinforced solids: some theoretical principles. Mech. Phys. Solids 11: 357–372.ADSCrossRefMATH
  18. 18.
    Hill, R. 1964. Theory of mechanical properties of fibre-strengthened materials. I. Elastic behaviour. Mech. Phys. Solids 12:199–212.MathSciNetADSCrossRef
  19. 19.
    Jaswon, M. A., Gillis, P. P., and Mark, R. E. 1968. The elastic constants of crystalline native cellulose. Proc. Roy. Soc. (London) A 306:389–412.ADS
  20. 20.
    Mark, R. E. 1972. Mechanical behavior of the molecular com ponents of fibers, “Theory and Design of Wood and Fiber Composite Materials,” B. A. Jayne, ed., Syracuse Univ. Press 49–82.
  21. 21.
    Norimoto, M., Hayashi, S., and Yamada, T., 1978. Anisotropy of dielectric constant in coniferous wood. Holzforsch32 (5):167–172.CrossRef
  22. 22.
    Ohgama, T., Masuda, M., and Yamada, T. 1977. Stress distri bution within cell wall of wood subjected to tensile force in transverse direction (in Japanese). Soc. Materials Sei. (Japan) 26:433–438.
  23. 23.
    Preston, R. D. 1974. “The Physical Biology of Plant Cell Walls,” Chapman and Hall, London.
  24. 24.
    Sarkanan, K. V., and Ludwig, C. H. (eds.). 1971. “Lignins: Occurrence, Formation, Structure and Reactions,” Wiley- Interscience, New York.
  25. 25.
    Sarko, A., and Muggli, R. 1974. Packing analysis of carbo hydrates and polysaccharides. III. Valonia cellulose” and cellulose II.Macromolecules 7:486–494ADSCrossRef
  26. 26.
    Tang, R. C., and Hsu, N. N. 1973. Analysis of the relation ship between microstructure and elastic properties of the cell wall. Wood & Fiber 5:139–151.
  27. 27.
    Wardrop, A. B. 1964. The structure and formation of the cell wall in xylem, in: The Formation of Wood in Forest Trees,” M. H. Zimmerman, ed.. Academic Press, N. Y. 87–134.
  28. 28.
    Woodcock, Carrie. 1979. “The X-ray crystallographic analysis of the structure of native ramie cellulose,” M. S. Thesis, SUNY College of Environmental Science and Forestry, Syracuse, New York.

For further details log on website :
http://link.springer.com/chapter/10.1007/978-1-4684-8983-5_2

No comments:

Post a Comment

Advantages and Disadvantages of Fasting for Runners

Author BY   ANDREA CESPEDES  Food is fuel, especially for serious runners who need a lot of energy. It may seem counterintuiti...