Process for production of high density/high performance binderless boards from whole coconut husk Part 1: Lignin as intrinsic thermosetting binder resin

Published Date
May 2004, Vol.19(3):207–216, doi:10.1016/j.indcrop.2003.10.003

Author

Jan E.G van Dam ^a,,

Martien J.A van den Oever ^a

Wouter Teunissen ^a

Edwin R.P Keijsers ^a

Aurora G Peralta ^b

• aAgrotechnological & Food Innovations (A&F bv), PO Box 17, 6700 AA Wageningen, The Netherlands
• bFiber Processing and Utilisation Laboratory, Fiber Industrial Development Authority (FIDA), Bai Compound, Visayas Avenue Diliman, Quezon City Manila, Philippines

Received 24 January 2003. Accepted 8 October 2003. Available online 13 December 2003

Abstract

Coconuts are abundantly growing in coastal areas of tropical countries. The coconut husk is available in large quantities as residue from coconut production in many areas, which is yielding the coarse coir fibre. The husk comprises ca. 30 wt.% coir fibres and 70 wt.% pith. Both fibre and pith are extremely high in lignin and phenolic content. The lignin is typically for monocotyledonous plants rich in syringyl with appreciable amounts of p-hydroxyphenyl units. The coir fibre is composed for at least one third of Klason lignin while lower molecular weight phenolics can be found as extractives in considerable amounts, especially in younger nuts. The thermal behaviour of the original (chemically unmodified) lignin in the plant tissues at temperatures above 140 °C, where it melts and shows thermosetting properties, has been investigated. This property of the coconut husk lignin was explored for application as intrinsic resin in board production, utilising whole fresh husks. Based on this concept, a simple and efficient technology has been developed to produce high strength–high density panels, without addition of chemical binders. Technical details will be reported in following papers.

Keywords

Coconut husk

Coir fibre

Pith

Lignin

Thermal properties

TGA

DSC

Thermosetting

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• * 
  Corresponding author.

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