Surface modification of PCC filled cellulose paper by MOF-5 (Zn3(BDC)2) metal–organic frameworks for use as soft gas adsorption composite materials

Published Date
July 2017, Volume 24, Issue 7, pp 3051–3060

Author

• Qiang Yang
• Meiyun Zhang
• Shunxi SongEmail author
• Bin Yang

1. 1.
2. 2.
3. 3.
4. 4.
5. 5.

Original Paper

First Online: 

12 May 2017

DOI: 10.1007/s10570-017-1331-9

Cite this article as:

Yang, Q., Zhang, M., Song, S. et al. Cellulose (2017) 24: 3051. doi:10.1007/s10570-017-1331-9

Abstract

In this paper, composite materials made of cellulose paper and MOF-5 (Zn3(BDC)2) Metal organic frameworks (paper@MOF-5) materials, were prepared by an in situ synthesis method using precipitated calcium carbonate (PCC) filled cellulose papers. PCC fillers in the cellulose paper led to decreased inter-fiber bonds, thus facilitating the formation of small-sized MOF-5 crystals. The resultant cellulose paper@MOF-5 composites exhibited zeolite-like frameworks with high specific surface areas. The composite materials were characterized by XRD, ATR-FTIR, SEM and nitrogen adsorption analysis. The results supported the conclusion that the prepared cellulose paper@MOF-5 composite materials have great potential in gas (N2, CH4, H2, CO2, etc.) adsorption.

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