Blog List

Monday, 18 July 2016

Replacing formaldehyde by furfural in urea formaldehyde resin: effect on formaldehyde emission and physical–mechanical properties of particleboards

Published Date
First online: 

Title 

Replacing formaldehyde by furfural in urea formaldehyde resin: effect on formaldehyde emission and physical–mechanical properties of particleboards

  • Author 
  • Robab Ghafari 
  • Kazem DoostHosseini
  • Ali Abdulkhani
  • Sayed Ahmad Mirshokraie

Abstract

To diminish the formaldehyde emission, replacement of the formaldehyde by furfural in urea formaldehyde (UF) resin was investigated and its effect on formaldehyde emission and physical–mechanical properties of particleboard panels produced from poplar wood was examined. Resin type: Industrial UF, Laboratory UF, UF-Furfural (in 25 and 50 % replacement levels), and two press temperatures including 170 and 180 °C were considered as variables. Results indicated that formaldehyde emission and modulus of rupture (MOR) of panels reduced thereby replacing the formaldehyde by furfural in UF resin. Internal bonding (IB) of panels made using 50 % replacement-modified resin was superior to others. Water absorption of panels decreased after 2- and 24-h immersion of samples with modified resins, as opposed to thickness swelling. The minimum thickness swelling was observed in panels made by Industrial UF resin. It is noteworthy that formaldehyde emission enhanced by increasing the temperature from 170 to 180 °C, and also all physical–mechanical characteristics developed at 180 °C temperature.

References

  1. Akyüz KC, Nemli G, Baharoğlu M, Zekoviç E (2010) Effects of acidity of the particles and amount of hardener on the physical and mechanical properties of particleboard composite bonded with urea formaldehyde. Int J Adhes Adhes 30(3):166–169CrossRef
  2. Belgacem MN, Gandini A (2003) Furan-based adhesives. Handbook of adhesive technology. Marcel Dekker, New York, pp 615–634
  3. Boran S, Usta M, Gümüşkaya E (2011) Decreasing formaldehyde emission from medium density fiberboard panels produced by adding different amine compounds to urea formaldehyde resin. Int J Adhes Adhes 31(7):674–678CrossRef
  4. Conner AH (1996) Urea–formaldehyde adhesive resins. Polym Mater Encycl 11:8496–8501
  5. Despres A, Pizzi A, Vu C, Delmotte L (2010) Colorless formaldehyde-free urea resin adhesives for wood panels. Eur J Wood Prod 68(1):13–20CrossRef
  6. Dunky M (1998) Urea–formaldehyde (UF) adhesive resins for wood. Int J Adhes Adhes 18(2):95–107CrossRef
  7. EN 310 (1993) Wood-based panels: determination of modulus of elasticity in bending and of bending strength. CEN European Committee for Standardization
  8. EN 317 (1993) Particleboards and fibreboards: determination of swelling in thickness after immersion in water. CEN European Committee for Standardization
  9. EN 322 (1993) Wood-based panels: determination of moisture content. CEN European Committee for Standardization
  10. Garcia AM, Ortiz M, Martinez R, Ortiz P, Reguera E (2004) The condensation of furfural with urea. Ind Crops Prod 19:99–106CrossRef
  11. Jiang T, Gardner DJ, Baumann MGD (2002) Volatile organic compound emissions arising from the hot-pressing of mixed-hardwood particleboard. For Prod J 52(11):66–77
  12. JISA 5908 (1994) Standard test methods for evaluation formaldehyde emission from particleboards. UDC 691.14-413:674.817
  13. Ko K (1976) How to control pollution of formaldehyde for formaldehyde series thermosetting resin adhesives. Settyaku Kyokaishi 12(5):160–166
  14. Maloney TM (1993) Modern particleboard and dry-process fiberboard manufacturing. Miller Freeman Publications, San Francisco
  15. Park BD, Lee SM, Roh JK (2009) Effects of formaldehyde/urea mole ratio and melamine content on the hydrolytic stability of cured urea-melamine-formaldehyde resin. Eur J Wood Prod 67(1):121–123CrossRef
  16. Park BD, Kang EC, Park SB, Park JY (2011) Empirical correlations between test methods of measuring formaldehyde emission of plywood, particleboard and medium density fiberboard. Eur J Wood Prod 69(2):311–316CrossRef
  17. Pizzi A (1990) Furfural-enhanced formaldehyde emission from UF particleboard. Holz Roh- Werkst 48(10):376CrossRef
  18. Pizzi A (1994) Advanced wood adhesives technology. Marcel Dekker, New York, p 289
  19. Pizzi A (2003) Urea–formaldehyde adhesives. In: Pizzi A, Mittal KL (eds) Handbook of adhesive technology, revised and expanded. CRC Press, USA, pp 628–645CrossRef
  20. Que Z, Furuno T, Katoh S, Nishino Y (2007a) Effects of urea–formaldehyde resin mole ratio on the properties of particleboard. Build Environ 42(3):1257–1263CrossRef
  21. Que Z, Furuno T, Katoh S, Nishino Y (2007b) Evaluation of three test methods in determination of formaldehyde emission from particleboard bonded with different mole ratio in the urea–formaldehyde resin. Build Environ 42(3):1242–1249CrossRef
  22. Roffael E, Johnsson B, Engström B (2010) On the measurement of formaldehyde release from low-emission wood-based panels using the perforator method. Wood Sci Technol 44(3):369–377CrossRef
  23. Salem MZM, Böhm M, Beránková J, Srba J (2011) Effect of some manufacturing variables on formaldehyde release from particleboard: relationship between different test methods. Build Environ 46(10):1946–1953CrossRef
  24. Schneider MH, Phillips JG (2010) Furfural-urea resins and adhesives and their methods of production. US Patent 7,781,521, issued August 24
  25. Schultz TP (1990) Exterior plywood resin formulated from furfuryl alcohol and paraformaldehyde. Holzforschung 44(6):467–468CrossRef
  26. Tomita B (1980) How chemical structure of UF resin affects formaldehyde emission. Mokuzai Kogyo 35(5):193–199
  27. Wang W, Gardner DJ, Baumann MG (2002) Reviewed articles-volatile organic compound emissions during hot-pressing of southern pine particleboard: panel size effects and trade-off between press time and temperature. For Prod J Index 52(4):24–30
  28. Zorba T, Papadopoulou E, Hatjiissaak A, Paraskevopoulos KM, Chrissafis K (2008) Urea–formaldehyde resins characterized by thermal analysis and FTIR method. J Therm Anal Calorim 92(1):29–33CrossRef

For further details log on website :
http://link.springer.com/article/10.1007/s00107-016-1005-6

No comments:

Post a Comment

Advantages and Disadvantages of Fasting for Runners

Author BY   ANDREA CESPEDES  Food is fuel, especially for serious runners who need a lot of energy. It may seem counterintuiti...