Published Date
Original
Cite this article as:
Krause, K.C., Müller, M., Militz, H. et al. Eur. J. Wood Prod. (2016). doi:10.1007/s00107-016-1091-5
Abstract
Polypropylene wood flour composites made from short-rotation coppice (SRC) and low valued beech wood (Fagus sylvatica) were investigated with respect to their suitability for use in the production of wood–polymer composites (WPC). An industrial wood source consisting of spruce wood flour (Picea abies) was used as reference material. All composites were compounded on a co-rotating twin screw extruder containing either 60 or 70 wt% wood flour. Consolidation was done by profile extrusion. Mechanical and physical properties of the composites were investigated. The wood sources were characterized concerning their particle length and shape by the use of a dynamic optical particle analysis system. X-ray microtomography (µ-CT) was used to study the dispersion of wood particles and the internal composite structure. However, all composites based on alternative wood sources showed an equivalent performance regarding mechanical properties compared to the composite reference. Composites containing beech wood flour showed notably reduced water absorption rates, whereas the composites based on SRC wood flour revealed significantly reduced moisture content compared to reference composites. A different particle length distribution was depicted between the industrial wood source and three other investigated wood sources. Moreover, all wood flour sources were characterized by a mean aspect ratio up to 3:1. The X-ray microtomography illustrated morphological differences between composites. Based on the X-ray images, an alignment along the melt flow and a decent encapsulation by polypropylene were shown.
References
For further details log on website :
http://link.springer.com/article/10.1007/s00107-016-1091-5
Title
Enhanced water resistance of extruded wood–polypropylene composites based on alternative wood sources
Original
- First Online:
- 01 August 2016
DOI: 10.1007/s00107-016-1091-5
Abstract
Polypropylene wood flour composites made from short-rotation coppice (SRC) and low valued beech wood (Fagus sylvatica) were investigated with respect to their suitability for use in the production of wood–polymer composites (WPC). An industrial wood source consisting of spruce wood flour (Picea abies) was used as reference material. All composites were compounded on a co-rotating twin screw extruder containing either 60 or 70 wt% wood flour. Consolidation was done by profile extrusion. Mechanical and physical properties of the composites were investigated. The wood sources were characterized concerning their particle length and shape by the use of a dynamic optical particle analysis system. X-ray microtomography (µ-CT) was used to study the dispersion of wood particles and the internal composite structure. However, all composites based on alternative wood sources showed an equivalent performance regarding mechanical properties compared to the composite reference. Composites containing beech wood flour showed notably reduced water absorption rates, whereas the composites based on SRC wood flour revealed significantly reduced moisture content compared to reference composites. A different particle length distribution was depicted between the industrial wood source and three other investigated wood sources. Moreover, all wood flour sources were characterized by a mean aspect ratio up to 3:1. The X-ray microtomography illustrated morphological differences between composites. Based on the X-ray images, an alignment along the melt flow and a decent encapsulation by polypropylene were shown.
References
- Ab Ghani MH, Ahmad S (2011) The comparison of water absorption analysis between counterrotating and corotating twin-screw extruders with different antioxidants content in wood plastic composites. Adv Mater Sci Eng 2011(Article ID 406284):4. doi:10.1155/2011/406284
- Bengtsson M, Baillif ML, Oksman K (2007) Extrusion and mechanical properties of highly filled cellulose fibre–polypropylene composites. Compos A 38:1922–1931CrossRef
- Bledzki AK, Reihmane S, Gassan J (1998) Thermoplastics reinforced with wood fillers: a literature review. Polym Plast Technol Eng 37(4):451–468CrossRef
- Butylina S, Martikka O, Kärki T (2011) Properties of wood fibre-polypropylene composites: effect of wood fibre source. Appl Compos Mater 18(2):101–111CrossRef
- Carus M, Baltus W, Carrez D, Kaeb J, Zepnik S (2014a) Market study and database on bio-based polymers in the world capacities, production and applications: status quo and trends towards 2020. Market study on bio-based polymers in the world (http://www.bio-based.eu/markets:NovaInstitutGmbH). Accessed 15 May 2015
- Carus M, Eder A, Dammer L, Korte H, Scholz S, Essel R, Breitmayer E (2014b) Wood–plastic composites (WPC) and natural fibre composites (NFC): European and global markets 2012 and future trends (http://www.bio-based.eu/markets:Nova-InstitutGmbH). Accessed 15 May 2015
- Clemons C (2002) Wood–plastic composites in the United States the interfacing of two industries. Forest Prod J 52(6):10–18
- DIN 53734 (1991) Testing of plastics; Sieve analysis of powdered plastics with air-jet sieve apparatus. German Institute for Standardization (DIN), Berlin
- DIN EN 15534-1 (2014) Composites made from cellulose-based materials and thermoplastics (usually called wood–polymer composites (WPC) or natural fibre composites (NFC))—part 1: test methods for characterisation of compounds and products; German version EN 15534-1:2014. German Institute for Standardization (DIN), Berlin
- Eder M, Burgert I, Terziev N, Daniel G (2008) The effect of (induced) dislocations on the tensile properties of individual Norway spruce fibres. Holzforschung 62(1):77–81CrossRef
- EN ISO 1183-1 (2013) Plastics—methods for determining the density of non-cellular plastics—part 1: immersion method, liquid pyknometer method and titration method. European Committee for Standardization (CEN), Brussels
- EN ISO 178 (2010) Plastics—determination of flexural properties; German version EN ISO 178:2010 + A1:2013. European Committee for Standardization (CEN), Brussels
- EN ISO 179-1 (2010) Plastics—determination of charpy impact properties—part 1: non-instrumented impact test (ISO 179-1:2010); German version. European Committee for Standardization (CEN), Brussels
- EN ISO 527-1 (1996) Plastics—determination of tensile properties—part 1: general principles. European Committee for Standardization (CEN), Brussels
- Guo G, Park CB, Lee YH, Kim YS, Sain M (2007) Flame retarding effects of nanoclay on wood–fiber composites. Polym Eng Sci 47(3):330–336CrossRef
- H’ng Paik S S, Lee Ai N, Hang Chit M (2008) Physical and bending properties of injection moulded wood plastic composites boards. J Eng Appl Sci 3(5):13
- Häusler A, Scherer-Lorenzen M (2001) Sustainable forest management in Germany: the Ecosystem Approach of the Biodiversity Convention reconsidered’, BfN-Skripten, 51. German Federal Agency for Nature Conservation, Bonn, p 65
- Hristov VN, Krumova M, Vasileva S, Michler GH (2003) Modified polypropylene wood flour composites. II. Fracture, deformation, and mechanical properties. J Appl Polym Sci 92(2):1286–1292CrossRef
- Kim JW, Harper DP, Taylor AM (2008) Effect of wood species on water sorption and durability of wood–plastic composites. Wood Fiber Sci 40(4):519–531
- Klyosov AA (2007) Foreword-overview: wood–plastic composites. John Wiley & Sons, Hoboken, p 412. ISBN 978-0-470-14891-4CrossRef
- Krause A, Krause KC (2012) Relation between surface area and optimal concentration of coupling agent in WPC. In: 11th Pacific RIM bio-based composites symposium, Shizuoka-City, Japan, pp 176–85
- Kumari R, Takatani M, Uchiyama M, Okamoto T, Ito H (2007) Fundamental studies on wood/cellulose-plastic composites: effects of composition and cellulose dimension on the properties of cellulose/PP composite. J Wood Sci 53(6):470–480CrossRef
- Mankowski M, Morrell JJ (2000) Patterns of fungal attack in wood–plastic composites following exposure in a soil block test. Wood Fiber Sci 32(3):340–345
- Mantau U (2009) Holzrohstoffbilanz Deutschland: Szenarien des Holz-aufkommens und der Holzverwendung bis 2012 (Commodity balance of wood in Germany: analyses and scenarios of wood reserves and wood revenue till 2012) (in German). In: VTI agriculture and forestry research, vol 327. BMELV, Berlin, pp 27–36
- Mantau U, Prins K, Lindner M, Verkerk H, Eggers J, Leel N, Oldenburger J, Asikainen A, Anttila P (2010) Real potential for changes in growth and use of EU forests, final report, Hamburg, Germany, June 2010
- Michaeli W, Menges G (1989) Prediction of product properties in extrusion and injection molding. Adv Polym Tech 9(1):69–85CrossRef
- Migneault S, Koubaa A, Erchiqui F, Chaala A, Englund K, Wolcott MP, Krause C (2008) Effect of fiber length on processing and properties of extruded wood–fiber/HDPE composites. J Appl Polym Sci 110(2):1085–1092CrossRef
- Migneault S, Koubaa A, Erchiqui F, Chaala A, Englund K, Wolcott MP (2009) Effects of processing method and fiber size on the structure and properties of wood–plastic composites. Compos A 40:80–85CrossRef
- Müller M (2011) Influence of wood modification on the properties of polyvinyl chloride based wood polymer composites (WPC), Doctorial thesis (Georg-August University of Goettingen)
- Müller M, Grüneberg T, Militz H, Krause A, Radovanovic I (2012) Influence of various wood modifications on the properties of polyvinyl chloride/wood flour composites. J Appl Polym Sci 125(1):308–312CrossRef
- Najafi SK, Kiaefar A, Tajvidi M (2008) Effect of bark flour content on the hygroscopic characteristics of wood–polypropylene composites. J Appl Polym Sci 110:3116–3120CrossRef
- Niemz P (2005) Physik des Holzes und der Holzwerkstoffe (Physics of wood and wood-based materials) (in German). Institut für Baustoffe IfB (Zürich: ETH - Eidgenössische Technische Hochschule), 159
- Nygård P, Karlsen T, Leinsvang B, Tanem BS, Brachet P (2008) Extrusion-based wood fibre-PP composites: wood powder and pelletized wood fibres—a comparative study. Compos Sci Technol 68(15–16):3418–3424CrossRef
- Radovanovic I (2007) Verarbeitung und optimierung der rezeptur von wood plastic composites (WPC) [Manufacturing process and optimisation of product formulations of wood–plastic composites (WPC)] (in German). Thesis. University of Osnabrück, Osnabrück
- Rowell RM (2005) Handbook of wood chemistry and wood composites. CRC Press, Boca Raton
- Rowell RM, Ibach RE, James M, Thomas N (2009) Understanding decay resistance, dimensional stability and strength changes in heat-treated and acetylated wood. Wood Mat Sci Eng 4(1–2):14–22CrossRef
- Schirp A, Stender J (2010) Properties of extruded wood–plastic composites based on refiner wood fibres (TMP fibres) and hemp fibres. Eur J Wood Prod 68(2):219–231CrossRef
- Schirp A, Ibach RE, Pendleton DE, Wolcott MP (2008) Biological degradation of wood–plastic composites (WPC) and strategies for improving the resistance of WPC against biological decay. ACS Symp Ser 982:480–507CrossRef
- Sobczak L, Bruggemann O, Putz RF (2012a) Polyolefin composites with natural fibers and wood-modification of the fiber/filler-matrix interaction. J Appl Polym Sci 127(1):1–17CrossRef
- Sobczak L, Lang RW, Haider A (2012b) Polypropylene composites with natural fibers and wood—general mechanical property profiles. Compos Sci Technol 72:550–557CrossRef
- Stark NM, Berger MJ (1997) Effect of species and particle size on properties of wood-flour-filled polypropylene composites. In: Proceeding of functional fillers for thermoplastic and thermosets, San Diego, CA, 16
- Stark NM, Rowlands RE (2003) Effects of wood fiber characteristics on mechanical properties of wood/polypropylene composites. Wood Fiber Sci 35(2):167–174
- Steckel V, Clemons CM, Thoemen H (2007) Effects of material parameters on the diffusion and sorption properties of wood-flour/polypropylene composites. J Appl Polym Sci 103(2):752–763CrossRef
- Teuber L (2013) Characterization of the wood component of WPC via dynamic image analysis. In: First international conference on resource efficiency in interorganizational networks, ResEff 2013. University of Goettingen, Goettingen
- Valle GCX, Tavares MIB, Luetkmeyer L, Stael GC (2007) Effect of wood content on the thermal behavior and on the molecular dynamics of wood/plastic composites. Macromol Symp 258(1):113–118CrossRef
- Viksne A, Berzina R, Andersone I, Belkova L (2010) Study of plastic compounds containing polypropylene and wood derived fillers from waste of different origin. J Appl Polym Sci 117(1):368–377
- Wagenführ R (1996) Wood atlas/Holzatlas, 4th edn. Carl Hanser, Leipzig. ISBN 3-446-00900-0
- Wolcott MP, Englund K (1999) A technology review of wood–plastic composites. In: Wolcott MP, Tichy RJ, Bender DA (eds) International particleboard/composite materials symposium. Washington State University, Pullman, pp 103–112
For further details log on website :
http://link.springer.com/article/10.1007/s00107-016-1091-5
No comments:
Post a Comment